List of episodes:
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Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu

Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu

HD
SUB
 SUB

Short Flash specials streamed alongside with the series.

AnimeFreak is the best site to watch Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu SUB online GoGoAnime, or you can even watch Madan no Ou to Vanadis: Tigre-kun to Vanadi-chu DUB in HD quality at KissAnime.
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